A, classification and properties of nylon
classification:
1, according to the number of carbon atoms
of diamine and dibasic acid, composed of two monomer synthetic nylon: 46, 66,
610, 66, 613, 1010, 1313,
2, according to the monomer containing
named in the number of carbon atoms: nylon 4, 5, 6, 7, 8, 9, 11, 12, 13
Second, features:
1, nylon has good toughness, self
lubrication and wear resistance, chemical resistance, gas permeability, and oil
resistance, non-toxic, and the advantages of easy coloring, so the nylon is
widely applied in industry.
The technological characteristic of the
rheological properties of nylon, nylon: most for crystalline nylon resin, when
the temperature exceeds its melting point, the melt viscosity is small, the
melt liquidity is wonderful, should prevent excessive edge. Due to the melt
condensation speed at the same time, should prevent material blocking the
nozzle, runner and gate products caused by insufficient phenomenon. Mould
overflow boundary value of 0.03, and the melt viscosity are sensitive to
temperature and shear stress change, but is more sensitive to temperature,
lower viscosity of the melt from the cylinder temperature first.
Four, nylon nylon absorbent, water
absorption and the dry wet nylon in molding process, characterized by viscosity
fell sharply and mixed with surface silver bubble products, the products
obtained mechanical strength decreased, so the material must be dry before
processing.
Crystalline: in addition to the transparent
nylon, nylon mostly for the crystallization of polymer, high crystallinity and
tensile strength, abrasion resistance, hardness, lubricity, and so on a
performance improvement, thermal expansion coefficient and water tends to
decline, but bad for transparency and impact resistance. Had a greater
influence on the mold temperature on the crystallization, mould temperature
high crystallinity, die temperature bottom end of crystallinity.
Shrinkage: similar to other crystalline
plastics, nylon resin shrinkage rate larger problems, the maximum nylon with
crystallization of contraction, when products crystallinity big products
shrinkage increases, in the process of forming lower mold temperature,
increasing injection pressure, lower temperature will decrease the contraction,
but the internal stress of products is more easy to deformation. PA66 shrinkage
rate of 1.5 to 2%
Molding equipment: nylon molding, mainly
pay attention to prevent "nozzle flow delay phenomenon", so the nylon
material processing generally choose the self-locking type nozzle.
Products and moulds:
1, the products of wall thickness Do so
than for 150-200 between nylon, nylon products wall thickness below 0.8 mm
generally between 1-3.2 mm, and the products of contraction associated with
products of wall thickness, the thicker the thickness contraction.
2, exhaust nylon resin overflow boundary
value is about 0.03 mm, so the vent groove should be controlled below 0.025.
3, mold temperature products thin wall
molding mould heating control or require high crystallinity, required products
have certain flexibility of general use cold water temperature control.
Third, molding technology of nylon
Cylinder temperature: as nylon is a
crystalline polymer, so obvious, melting point of nylon polymer in the
injection molding of the selected material barrel temperature with the
performance of the resin itself, equipment and products of shape factors. Nylon
6 melt temperature is 225 ℃ at the bottom, nylon 66 is 260 ℃. * due to the poor
thermal stability of nylon, should not be so high temperature for a long time
to stay in the cylinder, lest cause the material color is yellow, due to the
liquidity of nylon is better at the same time, the temperature over flow
quickly after its melting point.
Injection pressure: nylon low melt
viscosity, good fluidity, but the cooling speed faster, the complex shape and
wall thickness thinner products are easily appear shortage problem, so still
need high injection pressure. Pressure is too high, usually products will
overflow edge problems; Pressure is too low, products can produce corrugated,
bubble, obvious welding scar or lack of product defects, most varieties of
nylon injection pressure does not exceed 120 mpa, the general selection within
60-100 mpa is meet the requirements of most of the products, as long as the
products don't appear bubbles, defects such as dents, generally do not want to
use high pressure maintaining pressure, so as not to cause internal stress
increased.
Injection speed: for nylon, injection speed
for quick profit, can prevent the ripples caused by too fast cooling, molding
shortage problem. Fast injection speed impact on the performance of the
products is not prominent. Mold temperature mold temperature on the
crystallinity and the molding shrinkage has certain influence,
anti-embrittlement high crystallinity, wear resistance, hardness and elastic
modulus increased, decreased water imbibition, products molding shrinkage rate
increase; Low mold temperature low crystallinity, good toughness and elongation
is higher.
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