In 1847 Jöns Jacob Berzelius produced the
first condensation polymer, polyester, from glycerin (propanetriol) and
tartaric acid.[4] Berzelius is also credited with originating the chemical
terms catalysis, polymer, isomer, and allotrope, although his original
definitions differ dramatically from modern usage. For example, he coined the
term "polymer" in 1833 to describe organic compounds which shared
identical empirical formulas but which differed in overall molecular weight,
the larger of the compounds being described as "polymers" of the
smallest. According to this (now obsolete) definition, glucose (C6H12O6) would
be a polymer of formaldehyde (CH2O).
The first man-made commercial plastic was
invented in Britain in 1861 by Alexander Parkes. He publicly demonstrated it at
the 1862 International Exhibition in London, calling the material he produced
"Parkesine." Derived from cellulose and nitric acid (nitrocellulose),
Parkesine could be heated, moulded, and retain its shape when cooled. It was,
however, expensive to produce, prone to cracking, and highly flammable.
In 1868, American inventor John Wesley
Hyatt developed a plastic material he named Celluloid, improving on Parkes'
invention by plasticizing the nitrocellulose with camphor so that it could be
processed into finished form and used as a photographic film. Together with his
brother Isaiah, Hyatt patented the first injection moulding machine in 1872.
This machine was relatively simple compared to machines in use today: it worked
like a large hypodermic needle, using a plunger to inject plastic through a
heated cylinder into a mould. The industry progressed slowly over the years,
producing products such as collar stays, buttons, and hair combs.
The German chemists Arthur Eichengrün and
Theodore Becker invented the first soluble forms of cellulose acetate in 1903,
which was much less flammable than cellulose nitrate. It was eventually made
available in a powder form from which it was readily injection moulded. Arthur
Eichengrün developed the first injection moulding press in 1919. In 1939,
Arthur Eichengrün patented the injection molding of plasticized cellulose
acetate.
The industry expanded rapidly in the 1940s
because World War II created a huge demand for inexpensive, mass-produced
products.In 1946, American inventor James Watson Hendry built the first screw
injection machine, which allowed much more precise control over the speed of
injection and the quality of articles produced.[9] This machine also allowed
material to be mixed before injection, so that colored or recycled plastic
could be added to virgin material and mixed thoroughly before being injected.
Today screw injection machines account for the vast majority of all injection
machines. In the 1970s, Hendry went on to develop the first gas-assisted
injection moulding process, which permitted the production of complex, hollow
articles that cooled quickly. This greatly improved design flexibility as well
as the strength and finish of manufactured parts while reducing production
time, cost, weight and waste.
The plastic injection moulding industry has
evolved over the years from producing combs and buttons to producing a vast
array of products for many industries including automotive, medical, aerospace,
consumer products, toys, plumbing, packaging, and construction.
Examples of polymers best suited for the
process
Most polymers, sometimes referred to as
resins, may be used, including all thermoplastics, some thermosets, and some
elastomers. Since 1995, the total number of available materials for injection
moulding has increased at a rate of 750 per year; there were approximately
18,000 materials available when that trend began. Available materials include
alloys or blends of previously developed materials, so product designers can
choose the material with the best set of properties from a vast selection.
Major criteria for selection of a material are the strength and function
required for the final part, as well as the cost, but also each material has
different parameters for moulding that must be taken into account.[10]:6 Common
polymers like epoxy and phenolic are examples of thermosetting plastics while
nylon, polyethylene, and polystyrene are thermoplastic.[1]:242 Until comparatively
recently, plastic springs were not possible, but advances in polymer properties
make them now quite practical. Applications include buckles for anchoring and
disconnecting outdoor-equipment webbing.
没有评论:
发表评论